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Leseprobe
Leseprobe
Inhalt
Preface. Acknowledgements. Contributors. Abbreviations. 1 Noncovalent Functionalization of Carbon Nanotubes (Claudia Backes and Andreas Hirsch). 1.1 Introduction. 1.2 Overview of Functionalization Methods. 1.3 The Noncovalent Approach. 1.4 Conclusion. References. 2 Supramolecular Assembly of Fullerenes and Carbon Nanotubes Hybrids (Ma Ãngeles Herranz, Beatriz M. Illescas, Emilio M. Perez and Nazario MartÃn). 2.1 Introduction. 2.2 Hydrogen Bonded C60 Donor Ensembles. 2.3 Concave exTTF Derivatives as Recognizing Motifs for Fullerene. 2.4 Noncovalent Functionalization of Carbon Nanotubes. 2.5 Summary and Outlook. Acknowledgements. References. 3 Properties of Fullerene-Containing Dendrimers (Juan-Jose Cid Martin and Jean-Francois Nierengarten). 3.1 Introduction. 3.2 Dendrimers with a Fullerene Core. 3.3 Fullerene-Rich Dendrimers. 3.4 Conclusions. Acknowledgements. References. 4 Novel Electron Donor Acceptor Nanocomposites (Hiroshi Imahori, Dirk M. Guldi and Shunichi Fukuzumi). 4.1 Introduction. 4.2 Electron Donor-Fullerene Composites. 4.3 Carbon Nanotubes. 4.4 Other Nanocarbon Composites. References. 5 Higher Fullerenes: Chirality and Covalent Adducts (Agnieszka Kraszewska, Francois Diederich and Carlo Thilgen). 5.1 Introduction. 5.2 The Chemistry of C70. 5.3 The Higher Fullerenes Beyond C70. 5.4 Concluding Remarks. Acknowledgement. References. 6 Application of Fullerenes to Nanodevices (Yutaka Matsuo and Eiichi Nakamura). 6.1 Introduction. 6.2 Synthesis of Transition Metal Fullerene Complexes. 6.3 Organometallic Chemistry of Metal Fullerene Complexes. 6.4 Synthesis of Multimetal Fullerene Complexes. 6.5 Supramolecular Structures of Penta(organo)[60]fullerene Derivatives. 6.6 Reduction of Penta(organo)[60]fullerenes to Generate Polyanions. 6.7 Photoinduced Charge Separation. 6.8 Photocurrent-Generating Organic and Organometallic Fullerene Derivatives. 6.9 Conclusion. References. 7 Supramolecular Chemistry of Fullerenes: Host Molecules for Fullerenes on the Basis of pi-pi Interaction (Takeshi Kawase). 7.1 Introduction. 7.2 Fullerenes as an Electron Acceptor. 7.3 Host Molecules Composed of Aromatic pi-systems. 7.4 Complexes with Host Molecules Based on Porphyrin pi Systems. 7.5 Complexes with Host Molecules Bearing a Cavity Consisting of Curved pi System. 7.6 The Nature of the Supramolecular Property of Fullerenes. References. 8 Molecular Surgery toward Organic Synthesis of Endohedral Fullerenes (Michihisa Murata, Yasujiro Murata and Koichi Komatsu). 8.1 Introduction. 8.2 Molecular-Surgery Synthesis of Endohedral C60 Encapsulating Molecular Hydrogen. 8.3 Chemical Functionalization of H2@C60. 8.4 Utilization of the Encapsulated H2 as an NMR Probe. 8.5 Physical Properties of an Encapsulated H2 in C60. 8.6 Molecular-Surgery Synthesis of Endohedral C70 Encapsulating Molecular Hydrogen. 8.7 Outlook. References. 9 New Endohedral Metallofullerenes: Trimetallic Nitride Endohedral Fullerenes (Marilyn M. Olmstead, Alan L. Balch, Julio R. Pinzon, Luis Echegoyen, Harry W. Gibson and Harry C. Dorn). 9.1 Discovery, Preparation, and Purification. 9.2 Structural Studies. 9.3 Summary and Conclusions. References. 10 Recent Progress in Chemistry of Endohedral Metallofullerenes (Takahiro Tsuchiya, Takeshi Akasaka and Shigeru Nagase). 10.1 Introduction. 10.2 Chemical Derivatization of Mono-Metallofullerenes. 10.3 Chemical Derivatization of Di-Metallofullerenes. 10.4 Chemical Derivatization of Trimetallic Nitride Template F ...